Issue 22, 2011
From the journal:

CrystEngComm

Solid-state transformation of the MOF [Ni2(bipy)1.5(PDC)2(H2O)2]·3.5H2O†

Ainhoa Calderón-Casado,a   Gotzone Barandika,*b   Begoña Bazán,a   Miren-Karmele Urtiaga,a   Oriol Vallcorba,c   Jordi Rius,c   Carles Miravittlesc  and  María-Isabel Arriortuaa  

* Corresponding authors

a Departamento de Mineralogía y Petrología, Facultad de Ciencia y Tecnología, Universidad del País Vasco (UPV/EHU), Apdo 644, Bilbao, Spain
Fax: +34-946013500
Tel: +34-946012534

b Departamento de Química Inorgánica, Facultad de Farmacia, Universidad del País Vasco (UPV/EHU), Paseo de la Universidad, 7, Vitoria-Gasteiz, Spain
E-mail: gotzone.barandika@ehu.es
Fax: +34-945013014
Tel: +34-945013080

c Institut de Ciència de Materials de Barcelona (CSIC), Campus UAB, Bellaterra, Catalunya, Spain

Abstract

The combination of non-centrosymmetric ligands and dipyridyl spacers produces a MOF that potentially can be porous with formula [Ni2(bipy)1.5(PDC)2(H2O)2]·3.5H2O (bipy = 4,4′-bipyridine and PDC = pyridine-2,5-dicarboxylate). Dehydration of this compound results in a new MOF in which the formation of additional bonds between the carboxylate groups of PDC and the metal ion has occurred. This solid-state transformation takes place with no significant changes in the coordination sphere of the metal ion, which is unusual for coordination polymers. Both compounds exhibit the same unprecedented topology where the connectivity between nodes is remarkably high.

Graphical abstract: Solid-state transformation of the MOF [Ni2(bipy)1.5(PDC)2(H2O)2]·3.5H2O

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Article information

DOI
https://doi.org/10.1039/C1CE05594A
Article type
Paper
Submitted
19 May 2011
Accepted
19 Aug 2011
First published
15 Sep 2011

CrystEngComm, 2011,13, 6831-6838

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Solid-state transformation of the MOF [Ni2(bipy)1.5(PDC)2(H2O)2]·3.5H2O

A. Calderón-Casado, G. Barandika, B. Bazán, M. Urtiaga, O. Vallcorba, J. Rius, C. Miravittles and M. Arriortua, CrystEngComm, 2011, 13, 6831 DOI: 10.1039/C1CE05594A

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