Temperature-dependent supramolecular isomerism in three zinc coordination polymers with pamoic acid and 1,4-bis(imidazol-1-ylmethyl)-benzene†
Abstract
Three supramolecular isomeric metal–organic frameworks (MOFs) have been synthesized at different temperatures, exhibiting a structural progression from 2D (4,4) layer structures (α and β) to a 3D acentric 3-fold diamondoid network (γ).