Issue 17, 2011
From the journal:

CrystEngComm

Solvent-induced 1,3-N,S- vs. 1,5-S,S′-coordination in the NiII complex [Ni{p-Me2NC6H4NHC(S)NP(S)(OiPr)2}2]†

Maria G. Babashkina,*a   Damir A. Safin,a   Monika Srebro,b   Piotr Kubisiak,b   Mariusz P. Mitoraj,*b   Michael Boltec  and  Yann Garciaa  

* Corresponding authors

a Institute of Condensed Matter and Nanosciences, MOST - Inorganic Chemistry, Université Catholique de Louvain, Place L. Pasteur 1, Louvain-la-Neuve, Belgium
E-mail: maria.babashkina@ksu.ru
Fax: +32(0) 1047 2330
Tel: +32(0) 1047 2831

b Department of Theoretical Chemistry, Faculty of Chemistry, Jagiellonian University, R. Ingardena 3, Cracow, Poland
E-mail: mitoraj@chemia.uj.edu.pl

c Institut für Anorganische Chemie J.-W.-Goethe-Universität, Frankfurt/Main, Germany

Abstract

Reaction of the deprotonated N-thiophosphorylated thiourea p-Me2NC6H4NHC(S)NHP(S)(OiPr)2 (HL) with NiCl2 leads to violet [Ni(L-1,3-N,S)2] or dark violet [Ni(L-1,5-S,S′)2]·(CH3)2C[double bond, length as m-dash]O crystals that were isolated by recrystallization from a mixture of CH2Cl2 or acetone, respectively, and n-hexane.

Graphical abstract: Solvent-induced 1,3-N,S- vs. 1,5-S,S′-coordination in the NiII complex [Ni{p-Me2NC6H4NHC(S)NP(S)(OiPr)2}2]

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Article information

DOI
https://doi.org/10.1039/C1CE05387F
Article type
Communication
Submitted
30 Mar 2011
Accepted
16 Jun 2011
First published
20 Jul 2011

CrystEngComm, 2011,13, 5321-5327

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Solvent-induced 1,3-N,S- vs. 1,5-S,S′-coordination in the NiII complex [Ni{p-Me2NC6H4NHC(S)NP(S)(OiPr)2}2]

M. G. Babashkina, D. A. Safin, M. Srebro, P. Kubisiak, M. P. Mitoraj, M. Bolte and Y. Garcia, CrystEngComm, 2011, 13, 5321 DOI: 10.1039/C1CE05387F

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