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Issue 15, 2011
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Crystal engineering with dithiadiazolyl radicals

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The dithiadiazolyl radicals are a group of heterocyclic sulfur–nitrogen-containing neutral radicals. These molecules have received a great deal of attention due to their potential as building blocks for the development of molecular magnets and molecular conductors. Both magnetic and conducting properties are directly related to solid-state structure, and as a result dithiadiazolyl radicals have been the target of numerous systematic studies into the effects of molecular structure on crystal structure. This article will trace the advances in understanding of the factors affecting solid-state structure in this interesting class of molecules.

Graphical abstract: Crystal engineering with dithiadiazolyl radicals

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Article information

18 Feb 2011
11 Apr 2011
First published
16 May 2011

CrystEngComm, 2011,13, 4793-4805
Article type

Crystal engineering with dithiadiazolyl radicals

D. A. Haynes, CrystEngComm, 2011, 13, 4793
DOI: 10.1039/C1CE05217A

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