Issue 8, 2011
From the journal:

CrystEngComm

New organically decorated cadmium halides incorporating the second or the third inorganic anionic groups†

Juan Jin,a   Ming-Jun Jia,b   Yu Peng,a   Jie-Hui Yu*ac  and  Ji-Qing Xu*a  

* Corresponding authors

a College of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, P. R. China
E-mail: jiehuiyu@yahoo.com.cn, xjq@mail.jlu.edu.cn

b Key Laboratory of Surface and Interface Chemistry of Jilin Province, College of Chemistry, Jilin University, Qianjin Road 2699, Changchun, P. R. China

c State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, Jiangsu, P. R. China

Abstract

The room-temperature incorporation of the additional inorganic anionic groups SCN− and SO42− into the CdX2-piperazine (pip) system in acidic H2O/C2H5OH solutions generated the first example of a piperazinium-templated 1-D tube-like cadmium–bromothiocyanato sulfate [H2pip]4[Cd3Br8(SCN)2(SO4)2(H2O)]·4H2O 1 and the isostructural 1-D ribboned cadmium–halothiocyanato coordination polymers [CdX(SCN)L] [X− = Br−2, I−3; L = SC(OC2H5)[double bond, length as m-dash]NH2] with the ancillary organic S-donor ligand L. L was derived from the in situ nucleophilic addition reaction between the SCN−group and the C2H5OH solvent.

Graphical abstract: New organically decorated cadmium halides incorporating the second or the third inorganic anionic groups

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Article information

DOI
https://doi.org/10.1039/C1CE05038A
Article type
Paper
Submitted
11 Jan 2011
Accepted
31 Jan 2011
First published
25 Feb 2011

CrystEngComm, 2011,13, 2942-2947

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New organically decorated cadmium halides incorporating the second or the third inorganic anionic groups

J. Jin, M. Jia, Y. Peng, J. Yu and J. Xu, CrystEngComm, 2011, 13, 2942 DOI: 10.1039/C1CE05038A

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