Issue 15, 2011
From the journal:

CrystEngComm

Three novel supramolecular hybrid compounds based on keggin polytungstates†

Li-Na Xiao,a   Yan Wang,a   Cheng-Ling Pan,b   Jia-Ning Xu,a   Tie-Gang Wang,a   Hong Ding,a   Zhong-Min Gao,a   Da-Fang Zheng,a   Xiao-Bing Cui*a  and  Ji-Qing Xu*a  

* Corresponding authors

a College of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, China
E-mail: cuixb@mail.jlu.edu.cn, xjq@mail.jlu.edu.cn

b School of Materials Science and Engineering, Anhui University of Science & Technology, Huainan, Anhui, China

Abstract

Three novel supramolecular compounds [PWVI10.5WV1.5O40][Cu(2, 2′-bpy)2]4.5 (1), [CuI(Phen)2]4[CuI5Cl4(Phen)4][PWVI10WV2O40]2·4H2O(2) and [CuI(Phen)2]4[CuI5Cl4(Phen)4][BWVI12O40]2·2H2O(3) (bpy = bipyridine, Phen = 1,10-Phenanthroline) have been synthesized and characterized by IR, UV-Vis, TG, XRD, elemental analyses and single crystal X-ray diffraction analyses. Compound 1 is the first example of a hybrid compound which is constructed from polyoxometalates and supramolecular noncovalent coordination cages. Both compounds 2 and 3 are constructed from two different types of building blocks: polyoxometalates and metal halide fragments.

Graphical abstract: Three novel supramolecular hybrid compounds based on keggin polytungstates

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Article information

DOI
https://doi.org/10.1039/C0CE00897D
Article type
Paper
Submitted
26 Nov 2010
Accepted
03 May 2011
First published
10 Jun 2011

CrystEngComm, 2011,13, 4878-4885

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Three novel supramolecular hybrid compounds based on keggin polytungstates

L. Xiao, Y. Wang, C. Pan, J. Xu, T. Wang, H. Ding, Z. Gao, D. Zheng, X. Cui and J. Xu, CrystEngComm, 2011, 13, 4878 DOI: 10.1039/C0CE00897D

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