Issue 8, 2011

Two novel coordination polymers constructed from 2,2′-bipyridine-3,3′-dicarboxylic acid 1,1′-dioxide ligands

Abstract

Utilizing 2,2′-bipyridine-3,3′-dicarboxylic acid 1,1′-dioxide (H2BDCD) and CuCl2·2H2O (or Ba(NO3)2·6H2O) under hydrothermal conditions produces two novel coordination polymers {[Cu(BDCD)]·EtOH}n, 1 and [Ba(BDCD)·2H2O]n, 2. X-ray structure determination reveals that compound 1 shows a two-dimensional structure which is constructed by a well known (4,8) three-connected bimodal net, compound 2 exhibits a novel three-dimensional structure with interesting barium pillars as building blocks.

Graphical abstract: Two novel coordination polymers constructed from 2,2′-bipyridine-3,3′-dicarboxylic acid 1,1′-dioxide ligands

Supplementary files

Article information

Article type
Paper
Submitted
25 Nov 2010
Accepted
18 Feb 2011
First published
07 Mar 2011

CrystEngComm, 2011,13, 3040-3045

Two novel coordination polymers constructed from 2,2′-bipyridine-3,3′-dicarboxylic acid 1,1′-dioxide ligands

Y. Tang, M. Zhou, H. Wen, Z. Cao, X. Wang and S. Huang, CrystEngComm, 2011, 13, 3040 DOI: 10.1039/C0CE00884B

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