Issue 3, 2011

Linear extension of bithiophene compounds by the combination of C–N covalent bond cross-coupling and N–Ag coordinative bond formation

Abstract

Three one-dimensional AgI/imidazole/thiophene coordination polymers 1–3 bearing the same linear imidazole-terminated bithiophene linker but different counterions have been prepared by the first combination of carbon–nitrogen covalent bond cross-coupling and nitrogen–silver coordinative bond formation, in which 1 exhibits extraordinarily enhanced solid-state fluorescence and conductance because of its more condensely packed structure.

Graphical abstract: Linear extension of bithiophene compounds by the combination of C–N covalent bond cross-coupling and N–Ag coordinative bond formation

Supplementary files

Article information

Article type
Communication
Submitted
04 Oct 2010
Accepted
16 Nov 2010
First published
03 Dec 2010

CrystEngComm, 2011,13, 747-749

Linear extension of bithiophene compounds by the combination of C–N covalent bond cross-coupling and N–Ag coordinative bond formation

L. Wang, T. Tao, S. Fu, C. Wang, W. Huang and X. You, CrystEngComm, 2011, 13, 747 DOI: 10.1039/C0CE00689K

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