Issue 5, 2011
From the journal:

CrystEngComm

Near achiral metal–organic frameworks from conformationally flexible homochiral ligands resulted by the preferential formation of pseudo-inversion center in asymmetric unit†

Kyung Seok Jeong,a   Bo Hyung Lee,a   Qiaowei Li,b   Sang Beom Choi,c   Jaheon Kimc  and  Nakcheol Jeong*a  

* Corresponding authors

a Department of Chemistry, Korea University, Seoul, Korea
E-mail: njeong@korea.ac.kr

b Center for Reticular Chemistry, Department of Chemistry and Biochemistry, University of California-Los Angeles, Los Angeles, California, USA

c Department of Chemistry, Soongsil University, Seoul, Korea

Abstract

A near identical MOF from the reaction between a homochiral ligand and LaIII ion to that from racemic ligand was obtained due to the preferential formation of the pseudo-centrosymmetric arrangement in asymmetric units.

Graphical abstract: Near achiral metal–organic frameworks from conformationally flexible homochiral ligands resulted by the preferential formation of pseudo-inversion center in asymmetric unit

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Article information

DOI
https://doi.org/10.1039/C0CE00426J
Article type
Communication
Submitted
19 Jul 2010
Accepted
14 Oct 2010
First published
02 Nov 2010

CrystEngComm, 2011,13, 1277-1279

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Near achiral metal–organic frameworks from conformationally flexible homochiral ligands resulted by the preferential formation of pseudo-inversion center in asymmetric unit

K. S. Jeong, B. H. Lee, Q. Li, S. B. Choi, J. Kim and N. Jeong, CrystEngComm, 2011, 13, 1277 DOI: 10.1039/C0CE00426J

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