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Issue 44, 2011
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Carbohydrate-based pseudo-dipeptides: new ligands for the highly enantioselective Ru-catalyzed transfer hydrogenation reaction

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Abstract

Ruthenium-complexes of novel carbohydrate based pseudo-dipeptide ligands effectively and selectively catalyze the reduction of a broad range of arylalkyl ketones under ATH conditions. Excellent enantioselectivities (>99% ee) are obtained using aminosugars as the sole source of chirality.

Graphical abstract: Carbohydrate-based pseudo-dipeptides: new ligands for the highly enantioselective Ru-catalyzed transfer hydrogenation reaction

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Publication details

The article was received on 12 Aug 2011, accepted on 20 Sep 2011 and first published on 30 Sep 2011


Article type: Communication
DOI: 10.1039/C1CC15024C
Citation: Chem. Commun., 2011,47, 12188-12190

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    Carbohydrate-based pseudo-dipeptides: new ligands for the highly enantioselective Ru-catalyzed transfer hydrogenation reaction

    M. Coll, O. Pàmies, H. Adolfsson and M. Diéguez, Chem. Commun., 2011, 47, 12188
    DOI: 10.1039/C1CC15024C

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