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Issue 41, 2011
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Matrix-dependent cooperativity in spin crossover Fe(pyrazine)Pt(CN)4 nanoparticles

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Abstract

Anisotropic nanoparticles of the Fe(pyrazine)Pt(CN)4 network were prepared embedded in various matrices that revealed to have a dramatic effect on the cooperative spin crossover phenomena. By a judicious choice of the nature of the matrix and the control of interparticle distances, a hysteresis of 15 K was achieved close to room temperature for such nano-objects.

Graphical abstract: Matrix-dependent cooperativity in spin crossover Fe(pyrazine)Pt(CN)4 nanoparticles

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Publication details

The article was received on 22 Jul 2011, accepted on 09 Sep 2011 and first published on 21 Sep 2011


Article type: Communication
DOI: 10.1039/C1CC14463D
Citation: Chem. Commun., 2011,47, 11501-11503
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    Matrix-dependent cooperativity in spin crossover Fe(pyrazine)Pt(CN)4 nanoparticles

    Y. Raza, F. Volatron, S. Moldovan, O. Ersen, V. Huc, C. Martini, F. Brisset, A. Gloter, O. Stéphan, A. Bousseksou, L. Catala and T. Mallah, Chem. Commun., 2011, 47, 11501
    DOI: 10.1039/C1CC14463D

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