Issue 40, 2011
From the journal:

Chemical Communications

Directional photoinduced electron transfer in paraquat silicate thin films containing entrapped ruthenium(ii)-tris(bathophenanthroline-disulfonate)†

Scott A. Trammell,*a   Stanislav Tsoi,a   Brett Martin,a   Brian J. Melde,a   Martin M. Moorea  and  Walter J. Dressicka  

* Corresponding authors

a Center for Bio/Molecular Science & Engineering, Naval Research Laboratory, Washington, DC USA
E-mail: scott.trammell@nrl.navy.mil
Fax: +1-202-767-9594
Tel: +1-202-404-6063

Abstract

We have demonstrated directional photoinduced electron transfer in paraquat silicate thin films containing entrapped ruthenium(II)-tris(bathophenanthroline-disulfonate (RuBPS). The films were made by electrochemically-induced hydrolysis of a silane analogue of paraquat with ruthenium(II)-tris(bathophenanthroline-disulfonate as its ion pair.

Graphical abstract: Directional photoinduced electron transfer in paraquat silicate thin films containing entrapped ruthenium(ii)-tris(bathophenanthroline-disulfonate)

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Article information

DOI
https://doi.org/10.1039/C1CC14084A
Article type
Communication
Submitted
07 Jul 2011
Accepted
19 Aug 2011
First published
19 Sep 2011

Chem. Commun., 2011,47, 11348-11350

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Directional photoinduced electron transfer in paraquat silicate thin films containing entrapped ruthenium(II)-tris(bathophenanthroline-disulfonate)

S. A. Trammell, S. Tsoi, B. Martin, B. J. Melde, M. M. Moore and W. J. Dressick, Chem. Commun., 2011, 47, 11348 DOI: 10.1039/C1CC14084A

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