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Issue 31, 2011
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Assembly of a family of mixed metal {Mo : V} polyoxometalates templated by TeO32: {Mo12V12Te3}, {Mo12V12Te2} and {Mo17V8Te}

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Abstract

The influence of the pyramidal heteroanion, TeO32 in the self-assembly of mixed metal (Mo/V) systems, is demonstrated by the isolation of three novel mixed-metal, mixed-valence architectures, {Mo12V12Te3} (1), {Mo12V12Te2} (2) and {Mo17V8Te} (3) with the tellurium centres exhibiting the novel μ8-TeO4 and μ9-TeO3 coordination modes while compounds 1 and 2 were discovered utilizing ESI mass spectrometry.

Graphical abstract: Assembly of a family of mixed metal {Mo : V} polyoxometalates templated by TeO32−: {Mo12V12Te3}, {Mo12V12Te2} and {Mo17V8Te}

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Article information


Submitted
12 May 2011
Accepted
08 Jun 2011
First published
06 Jul 2011

Chem. Commun., 2011,47, 8799-8801
Article type
Communication

Assembly of a family of mixed metal {Mo : V} polyoxometalates templated by TeO32: {Mo12V12Te3}, {Mo12V12Te2} and {Mo17V8Te}

M. N. Corella-Ochoa, H. N. Miras, A. Kidd, D. Long and L. Cronin, Chem. Commun., 2011, 47, 8799
DOI: 10.1039/C1CC12782A

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