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Issue 34, 2011
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Synthesis of 1,3,5-alternate azacalix[3]pyridine[3]pyrimidine and its complexation with fullerenesvia multiple π/π and CH/π interactions

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Abstract

Azacalix[3]pyridine[3]pyrimidine was synthesized efficiently by means of a [3+3] fragment coupling approach. Adopting a preorganized symmetric 1,3,5-alternate conformation, the macrocycle formed complexes with fullerenes through the multiple intramolecular π/π and CH/π interactions.

Graphical abstract: Synthesis of 1,3,5-alternate azacalix[3]pyridine[3]pyrimidine and its complexation with fullerenesvia multiple π/π and CH/π interactions

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Submitted
16 Mar 2011
Accepted
06 Jul 2011
First published
19 Jul 2011

Chem. Commun., 2011,47, 9690-9692
Article type
Communication

Synthesis of 1,3,5-alternate azacalix[3]pyridine[3]pyrimidine and its complexation with fullerenesvia multiple π/π and CH/π interactions

L. Wang, L. Zhao, D. Wang and M. Wang, Chem. Commun., 2011, 47, 9690
DOI: 10.1039/C1CC11514F

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