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Issue 9, 2011
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X-Ray crystal structure of a heterobimetallic Al–Zn-oxide complex

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Abstract

OH/R (R = H, Me, i-Bu) exchange was observed in reactions of [MesnacnacZn(μ-OH)]2 (1) with metal complexes LnMR, whereas DippnacnacAl(Me)OH reacts with MesnacnacZnH with elimination of H2 and formation of the heterobimetallic Al–Zn-oxide complex MesnacnacZnOAl(Me)Dippnacnac 2.

Graphical abstract: X-Ray crystal structure of a heterobimetallic Al–Zn-oxide complex

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Article information


Submitted
15 Dec 2010
Accepted
12 Jan 2011
First published
31 Jan 2011

Chem. Commun., 2011,47, 2676-2678
Article type
Communication

X-Ray crystal structure of a heterobimetallic Al–Zn-oxide complex

S. Schulz, J. Spielmann, D. Bläser and C. Wölper, Chem. Commun., 2011, 47, 2676
DOI: 10.1039/C0CC05599A

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