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Issue 14, 2011
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Electrochemical evidence for catalyticwater oxidation mediated by a high-valent cobalt complex

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Abstract

The pH-dependent electrochemical behavior for a Co(II) complex, [Co(Py5)(OH2)](ClO4)2 (1; Py5 = 2,6-(bis(bis-2-pyridyl)methoxymethane)pyridine), indicates consecutive (proton-coupled) oxidation steps furnish a CoIV species that catalyzes the oxidation of water in basic media.

Graphical abstract: Electrochemical evidence for catalyticwater oxidation mediated by a high-valent cobalt complex

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Publication details

The article was received on 12 Dec 2010, accepted on 08 Feb 2011 and first published on 28 Feb 2011


Article type: Communication
DOI: 10.1039/C0CC05522K
Citation: Chem. Commun., 2011,47, 4249-4251
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    Electrochemical evidence for catalyticwater oxidation mediated by a high-valent cobalt complex

    D. J. Wasylenko, C. Ganesamoorthy, J. Borau-Garcia and C. P. Berlinguette, Chem. Commun., 2011, 47, 4249
    DOI: 10.1039/C0CC05522K

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