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Issue 3, 2011
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Chemical tailoring of fullerene acceptors: synthesis, structures and electrochemical properties of perfluoroisopropylfullerenes

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Abstract

High-temperature syntheses of the new C60(i-C3F7)2,4,6 and C70(i-C3F7)2,4 isomers and their characterization by spectroscopic methods, X-ray crystallography, cyclic voltammetry and density functional theory provide compelling evidence that they are superior electron acceptors than trifluoromethylfullerenes.

Graphical abstract: Chemical tailoring of fullerene acceptors: synthesis, structures and electrochemical properties of perfluoroisopropylfullerenes

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Article information


Submitted
13 Aug 2010
Accepted
23 Sep 2010
First published
09 Nov 2010

Chem. Commun., 2011,47, 875-877
Article type
Communication

Chemical tailoring of fullerene acceptors: synthesis, structures and electrochemical properties of perfluoroisopropylfullerenes

N. B. Shustova, I. V. Kuvychko, D. V. Peryshkov, J. B. Whitaker, B. W. Larson, Y. Chen, L. Dunsch, K. Seppelt, A. A. Popov, S. H. Strauss and O. V. Boltalina, Chem. Commun., 2011, 47, 875
DOI: 10.1039/C0CC03247F

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