Issue 47, 2011

The metal–carbonyl⋯π(aryl) interaction as a supramolecular synthon for the stabilisation of transition metal carbonyl crystal structures

Abstract

M–carbonyl(lone pair)⋯π(aryl) interactions provide stability to their transition metal crystal structures. This supramolecular synthon usually leads to zero- or one-dimensional aggregation patterns; a rare example of a three-dimensional architecture based on the M–CO(lone pair)⋯π(aryl) synthon has also been revealed.

Graphical abstract: The metal–carbonyl⋯π(aryl) interaction as a supramolecular synthon for the stabilisation of transition metal carbonyl crystal structures

Supplementary files

Article information

Article type
Communication
Submitted
09 Sep 2011
Accepted
17 Oct 2011
First published
31 Oct 2011

Chem. Commun., 2011,47, 12682-12684

The metal–carbonyl⋯π(aryl) interaction as a supramolecular synthon for the stabilisation of transition metal carbonyl crystal structures

J. Zukerman-Schpector, I. Haiduc and E. R.T. Tiekink, Chem. Commun., 2011, 47, 12682 DOI: 10.1039/C1CC15579B

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