Issue 46, 2011
From the journal:

Chemical Communications

Facile “one pot” route to the novel benzazulene-type dye class: asymmetric, derivatizable, 5-7-6 fused ring puckered half BODIPY design†

Dhiraj P. Murale,a   Kang Mun Lee,b   Kibong Kima  and  David G. Churchill*a  

* Corresponding authors

a Molecular Logic Gate Laboratory, Department of Chemistry, Korea Advanced Institute of Science and Technology (KAIST), 373-1 Guseong-dong, Yuseong-gu, Daejeon, Republic of Korea
E-mail: dchurchill@kaist.ac.kr
Fax: +82 42-350-2810
Tel: +82 42-350-2845

b Department of Chemistry, Korea Advanced Institute of Science and Technology (KAIST), 373-1 Guseong-dong, Yuseong-gu, Daejeon, Republic of Korea

Abstract

A novel fluorescent difluoroboroazaoxobenzazulene dye has been synthesized from commercially available substrates in “one pot”; it was characterized structurally and spectroscopically, derivatized and finally compared to a related BODIPY system that demonstrates “turn-on” H+ (42-fold) and F− (∼5-fold) responses.

Graphical abstract: Facile “one pot” route to the novel benzazulene-type dye class: asymmetric, derivatizable, 5-7-6 fused ring puckered half BODIPY design

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Article information

DOI
https://doi.org/10.1039/C1CC15433H
Article type
Communication
Submitted
01 Sep 2011
Accepted
13 Oct 2011
First published
25 Oct 2011

Chem. Commun., 2011,47, 12512-12514

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Facile “one pot” route to the novel benzazulene-type dye class: asymmetric, derivatizable, 5-7-6 fused ring puckered half BODIPY design

D. P. Murale, K. M. Lee, K. Kim and D. G. Churchill, Chem. Commun., 2011, 47, 12512 DOI: 10.1039/C1CC15433H

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