Issue 45, 2011
From the journal:

Chemical Communications

Pd2+⋯O3SR− interaction encourages anion encapsulation of a quadruply-stranded Pd complex to achieve chirality or high solubility†

Ryo Sekiyaa  and  Reiko Kuroda*a  

* Corresponding authors

a Department of Life Sciences, Graduate School of Arts and Sciences, The University of Tokyo, 3-8-1 Komaba, Meguro-ku, Tokyo 153-8902, Japan
E-mail: ckuroda@mail.ecc.u-tokyo.ac.jp

Abstract

Pd2+⋯O3SR− and CH⋯O3SR− interactions were found to play a crucial role in the encapsulation of organic sulfonates in a quadruply-stranded complex of Pd2L4-type. We have successfully employed this feature to achieve chirality induction by complexation with chiral guests as well as solubility increase by dendronization.

Graphical abstract: Pd2+⋯O3SR− interaction encourages anion encapsulation of a quadruply-stranded Pd complex to achieve chirality or high solubility

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Article information

DOI
https://doi.org/10.1039/C1CC14982B
Article type
Communication
Submitted
11 Aug 2011
Accepted
06 Oct 2011
First published
18 Oct 2011

Chem. Commun., 2011,47, 12346-12348

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Pd2+⋯O3SR− interaction encourages anion encapsulation of a quadruply-stranded Pd complex to achieve chirality or high solubility

R. Sekiya and R. Kuroda, Chem. Commun., 2011, 47, 12346 DOI: 10.1039/C1CC14982B

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