Issue 38, 2011
From the journal:

Chemical Communications

Weak Ag⋯Ag and Ag⋯π interactions in templating regioselective single and double [2+2] reactions of N,N′-bis(3-(4-pyridyl)acryloyl)–hydrazine: synthesis of an unprecedented tricyclohexadecane ring system†

Ramkinkar Santra,a   Kaustuv Banerjeea  and  Kumar Biradha*a  

* Corresponding authors

a Department of Chemistry, Indian Institute of Technology, Kharagpur-721302, India
E-mail: kbiradha@chem.iitkgp.ernet.in
Fax: +91-3222-282252
Tel: +91-3222-283346

Abstract

Synthesis of a stereospecific four–twelve–four fused tricyclic compound containing a tetraamide macrocycle has been achieved by the solid state [2+2] reaction through utilization of Ag⋯Ag interaction. The influence of anions on crystal packing has been utilized for the synthesis of a regioselective mono cyclobutane compound via the Ag⋯π interactions.

Graphical abstract: Weak Ag⋯Ag and Ag⋯π interactions in templating regioselective single and double [2+2] reactions of N,N′-bis(3-(4-pyridyl)acryloyl)–hydrazine: synthesis of an unprecedented tricyclohexadecane ring system

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Article information

DOI
https://doi.org/10.1039/C1CC13994K
Article type
Communication
Submitted
04 Jul 2011
Accepted
09 Aug 2011
First published
22 Aug 2011

Chem. Commun., 2011,47, 10740-10742

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Weak Ag⋯Ag and Ag⋯π interactions in templating regioselective single and double [2+2] reactions of N,N′-bis(3-(4-pyridyl)acryloyl)–hydrazine: synthesis of an unprecedented tricyclohexadecane ring system

R. Santra, K. Banerjee and K. Biradha, Chem. Commun., 2011, 47, 10740 DOI: 10.1039/C1CC13994K

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