Issue 38, 2011
From the journal:

Chemical Communications

Oxidative properties of a nonheme Ni(ii)(O2) complex: Reactivity patterns for C–H activation, aromatic hydroxylation and heteroatom oxidation†

Reza Latifi,ab   Laleh Tahsini,ab   Devesh Kumar,*cd   G. Narahari Sastry,c   Wonwoo Nam*b  and  Sam P. de Visser*a  

* Corresponding authors

a Manchester Interdisciplinary Biocenter and School of Chemical Engineering and Analytical Science, University of Manchester, 131 Princess Street, Manchester M1 7DN, UK
E-mail: sam.devisser@manchester.ac.uk
Fax: +44 161 306 5201

b Department of Chemistry and Nano Science, Department of Bioinspired Science, Centre for Biomimetic Systems, Ewha Womans University, Seoul 120-750, Korea
E-mail: wwnam@ewha.ac.kr
Fax: +82 3277 4441

c Molecular Modelling Group, Indian Institute of Chemical Technology, Hyderabad 500-607, India
E-mail: dkclcre@yahoo.com

d Department of Applied Physics, School for Physical Sciences, Babasaheb Bhimrao Ambedkar University, Vidya Vihar, Rae Bareilly Road, Lucknow (U. P.) 226 025, India.

Abstract

Density functional theory calculations on the reactivity of a Ni(II)-superoxo complex in C–H bond activation, aromatic hydroxylation and heteroatom oxidation reactions have been explored; the Ni(II)-superoxo complex is able to react with substrates with weak C–H bonds and PPh3.

Graphical abstract: Oxidative properties of a nonheme Ni(ii)(O2) complex: Reactivity patterns for C–H activation, aromatic hydroxylation and heteroatom oxidation

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Article information

DOI
https://doi.org/10.1039/C1CC13993B
Article type
Communication
Submitted
04 Jul 2011
Accepted
17 Aug 2011
First published
02 Sep 2011

Chem. Commun., 2011,47, 10674-10676

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Oxidative properties of a nonheme Ni(II)(O2) complex: Reactivity patterns for C–H activation, aromatic hydroxylation and heteroatom oxidation

R. Latifi, L. Tahsini, D. Kumar, G. N. Sastry, W. Nam and S. P. de Visser, Chem. Commun., 2011, 47, 10674 DOI: 10.1039/C1CC13993B

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