Issue 37, 2011
From the journal:

Chemical Communications

Pt(ii)-activated coupling of aminoethylferrocene with benzonitrile. A facile access route to a new redox-active bis(ferrocenyl-amidine) anion sensor†

Daniel Nieto,a   Ana Ma González-Vadillo,*a   Sonia Bruña,a   César J. Pastor,b   Angel E. Kaifer*c  and  Isabel Cuadrado*a  

* Corresponding authors

a Departamento de Química Inorgánica, Facultad de Ciencias, Universidad Autónoma de Madrid, Cantoblanco, Madrid, Spain
E-mail: anam.gonzalez@uam.es, isabel.cuadrado@uam.es
Fax: +34 91 497 4833
Tel: +34 91 497 4843

b Laboratorio de Difracción de Rayos X, SIDI, Universidad Autónoma de Madrid, Spain

c Center for Supramolecular Science and Department of Chemistry, University of Miami, Coral Gables, USA
E-mail: akaifer@miami.edu

Abstract

A new heterometallic electroactive compound having the ferrocenyl moiety attached to the platinum atom through an amidine functionality has been prepared viaPt(II)-mediated nucleophilic addition of β-aminoethylferrocene to a benzonitrile ligand. This neutral receptor shows remarkable electrochemical anion-sensing redox response to H2PO4−.

Graphical abstract: Pt(ii)-activated coupling of aminoethylferrocene with benzonitrile. A facile access route to a new redox-active bis(ferrocenyl-amidine) anion sensor

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Article information

DOI
https://doi.org/10.1039/C1CC13704B
Article type
Communication
Submitted
21 Jun 2011
Accepted
28 Jul 2011
First published
15 Aug 2011

Chem. Commun., 2011,47, 10398-10400

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Pt(II)-activated coupling of aminoethylferrocene with benzonitrile. A facile access route to a new redox-active bis(ferrocenyl-amidine) anion sensor

D. Nieto, A. M. xmlns="http://www.rsc.org/schema/rscart38"> <. González-Vadillo, S. Bruña, C. J. Pastor, A. E. Kaifer and I. Cuadrado, Chem. Commun., 2011, 47, 10398 DOI: 10.1039/C1CC13704B

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