Issue 37, 2011
From the journal:

Chemical Communications

Spin crossover in the cyanide-bridged MoVMnIII single-chain magnet containing FeII cations†

Jung Hee Yoon,a   Dae Won Ryu,a   Sang Yup Choi,a   Hyoung Chan Kim,b   Eui Kwan Koh,c   Jun Taod  and  Chang Seop Hong*a  

* Corresponding authors

a Department of Chemistry, Research Institute for Natural Sciences, Korea University, Seoul 136-7, Korea
E-mail: cshong@korea.ac.kr

b National Fusion Research Institute, Daejeon 305-333, Korea

c Nano-Bio System Research Team, Korea Basic Science Institute, Seoul 136-713, Korea

d Department of Chemistry, Xiamen University, Xiamen 361005, People's Republic of China

Abstract

A 1D MoVMnIII chain compound balanced by {Fe[HC(3,5-Me2pz)3]2}2+ dications was prepared. This complex displays a typical single-chain magnet character associated with the MoVMnIII chain and a spin crossover phenomenon arising from cationic Fe(II) subunits. The spin crossover behavior tends to slightly affect single-chain magnetic properties at low temperature.

Graphical abstract: Spin crossover in the cyanide-bridged MoVMnIII single-chain magnet containing FeII cations

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Article information

DOI
https://doi.org/10.1039/C1CC13627E
Article type
Communication
Submitted
18 Jun 2011
Accepted
27 Jul 2011
First published
11 Aug 2011

Chem. Commun., 2011,47, 10416-10418

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Spin crossover in the cyanide-bridged MoVMnIII single-chain magnet containing FeII cations

J. H. Yoon, D. W. Ryu, S. Y. Choi, H. C. Kim, E. K. Koh, J. Tao and C. S. Hong, Chem. Commun., 2011, 47, 10416 DOI: 10.1039/C1CC13627E

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