Issue 33, 2011
From the journal:

Chemical Communications

Synthesis of ketones by palladium-catalysed desulfitative reaction of arylsulfinic acids with nitriles†

Tao Miaoa  and  Guan-Wu Wang*ab  

* Corresponding authors

a Hefei National Laboratory for Physical Sciences at Microscale, CAS Key Laboratory of Soft Matter Chemistry, Joint Laboratory of Green Synthetic Chemistry and Department of Chemistry, University of Science and Technology of China, Hefei, P. R. China
E-mail: gwang@ustc.edu.cn
Fax: +86 551 3607864
Tel: +86 551 3607864

b State KeyLaboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou, PR. China

Abstract

Palladium-catalysed desulfitative addition of arylsulfinic acids to aryl and alkyl nitriles with 2,2′-bipyridine as a ligand afforded a variety of aryl ketonesviahydrolysis of ketimine intermediates.

Graphical abstract: Synthesis of ketones by palladium-catalysed desulfitative reaction of arylsulfinic acids with nitriles

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Article information

DOI
https://doi.org/10.1039/C1CC13352G
Article type
Communication
Submitted
06 Jun 2011
Accepted
05 Jul 2011
First published
18 Jul 2011

Chem. Commun., 2011,47, 9501-9503

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Synthesis of ketones by palladium-catalysed desulfitative reaction of arylsulfinic acids with nitriles

T. Miao and G. Wang, Chem. Commun., 2011, 47, 9501 DOI: 10.1039/C1CC13352G

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