Issue 31, 2011
From the journal:

Chemical Communications

An uncommon highly oxidized multiple bonded Re28+ species†

Gina M. Chiarella,a   F. Albert Cottona  and  Carlos A. Murillo*a  

* Corresponding authors

a Department of Chemistry, P. O. Box 3012, Texas A&M University, College Station, Texas 77842-3012, USA
E-mail: murillo@tamu.edu
Fax: +703 292 9037
Tel: +703 292 4970

Abstract

A long-sought metal–metal bonded species with an M28+ core has been structurally characterized. The diamagnetic compound {[Re2(hpp)3(OH)(O3SCF3)]2(μ-O)2}(O3SCF3)2, 2, has two σ2π4 electron-poor triple-bonded Re28+ units embraced by three bicyclic guanidinate ligands (hpp) and axial OH and triflate groups; the two dimetal units are held together by bridging oxo-groups.

Graphical abstract: An uncommon highly oxidized multiple bonded Re28+ species

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Article information

DOI
https://doi.org/10.1039/C1CC13193A
Article type
Communication
Submitted
30 May 2011
Accepted
14 Jun 2011
First published
08 Jul 2011

Chem. Commun., 2011,47, 8940-8942

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An uncommon highly oxidized multiple bonded Re28+ species

G. M. Chiarella, F. A. Cotton and C. A. Murillo, Chem. Commun., 2011, 47, 8940 DOI: 10.1039/C1CC13193A

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