Issue 33, 2011
From the journal:

Chemical Communications

Homochiral 3D metal–organic frameworks from chiral 1D rods: 6-way helical packing†

Sung Min Shin,a   Dohyun Moon,b   Kyung Seok Jeong,a   Jaheon Kim,c   Praveen K. Thallapally*d  and  Nakcheol Jeong*ae  

* Corresponding authors

a Department of Chemistry, Korea University, Seoul, Korea
E-mail: njeong@korea.ac.kr
Fax: +82-2-3290-3121
Tel: +82-2-3290-3136

b Beamline Division, Pohang Accelerator Laboratory/POSTECH San-31 Hyoja-Dong, Nam-Gu Pohang, Kyung Buk 790-784, Korea

c Department of Chemistry, Soongsil University, Seoul 156-743, Korea

d Pacific Northwest National Laboratory, Richland, WA, USA
E-mail: praveen.thallapally@pnnl.gov
Fax: +1-509-371-7249
Tel: +1-509-371-7183

e Korea Basic Science Institute, Seoul Centre, Seoul, Korea

Abstract

The chiral 3D MOFs resulted from the packing of chiral 1D SBBs were studied. It was demonstrated that the final packing pattern is sensitively dependent on the dimension of SBBs. In addition, we were able to identify a new plywood-like network from ligand 2H2 exhibiting an unprecedented six-way chiral helical packing motif, which extends the list of invariant rod packings.

Graphical abstract: Homochiral 3D metal–organic frameworks from chiral 1D rods: 6-way helical packing

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Article information

DOI
https://doi.org/10.1039/C1CC12908B
Article type
Communication
Submitted
18 May 2011
Accepted
29 Jun 2011
First published
20 Jul 2011

Chem. Commun., 2011,47, 9402-9404

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Homochiral 3D metal–organic frameworks from chiral 1D rods: 6-way helical packing

S. M. Shin, D. Moon, K. S. Jeong, J. Kim, P. K. Thallapally and N. Jeong, Chem. Commun., 2011, 47, 9402 DOI: 10.1039/C1CC12908B

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