Issue 34, 2011
From the journal:

Chemical Communications

pH Influenced molecular switching with micelle bound cavitands†

Yeon Joo Kim,a   Mark T. Leka  and  Michael P. Schramm*a  

* Corresponding authors

a California State University Long Beach, Department of Chemistry and Biochemistry, 1250 Bellflower Blvd., Long Beach, CA, USA
E-mail: schramm@csulb.edu
Fax: +1 562-985-8557
Tel: +1 562-985-1866

Abstract

A series of resorcinarene host–amphiphilic guest complexes have been developed where guest orientation in the host is drastically influenced by pH. Guests appended with a trimethylammonium and a tert-butyl group switch orientation by 180° in response to a buildup of negative charge in the cavitand host.

Graphical abstract: pH Influenced molecular switching with micelle bound cavitands

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Article information

DOI
https://doi.org/10.1039/C1CC12901E
Article type
Communication
Submitted
17 May 2011
Accepted
10 Jul 2011
First published
01 Aug 2011

Chem. Commun., 2011,47, 9636-9638

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pH Influenced molecular switching with micelle bound cavitands

Y. J. Kim, M. T. Lek and M. P. Schramm, Chem. Commun., 2011, 47, 9636 DOI: 10.1039/C1CC12901E

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