Issue 37, 2011
From the journal:

Chemical Communications

A one-dimensional coordination polymer exhibiting simultaneous spin-crossover and semiconductor behaviour†

Wei Xue,a   Bao-Ying Wang,a   Jie Zhu,a   Wei-Xiong Zhang,a   Yue-Biao Zhang,a   Hai-Xia Zhaob  and  Xiao-Ming Chen*a  

* Corresponding authors

a MOE Laboratory of Bioinorganic and Synthetic Chemistry, State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry & Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, P.R. China
E-mail: cxm@mail.sysu.edu.cn

b State Key Laboratory of Physical Chemistry of Solid Surface and College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, P.R. China

Abstract

A rare organosulfur one-dimensional coordination polymer, [Co(C9H6NS)2], was synthesized by the reaction between the 8-mercaptoquinoline and cobalt acetate salts in EtOH, which shows strong magnetic coupling and the presence of spin-glassy and spin-crossover phenomena with simultaneous semiconductor behaviour.

Graphical abstract: A one-dimensional coordination polymer exhibiting simultaneous spin-crossover and semiconductor behaviour

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Article information

DOI
https://doi.org/10.1039/C1CC12852C
Article type
Communication
Submitted
16 May 2011
Accepted
03 Aug 2011
First published
22 Aug 2011

Chem. Commun., 2011,47, 10233-10235

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A one-dimensional coordination polymer exhibiting simultaneous spin-crossover and semiconductor behaviour

W. Xue, B. Wang, J. Zhu, W. Zhang, Y. Zhang, H. Zhao and X. Chen, Chem. Commun., 2011, 47, 10233 DOI: 10.1039/C1CC12852C

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