Issue 28, 2011
From the journal:

Chemical Communications

New environmentally friendly catalysts containing Pd–interstitial carbon made from Pd–glucose precursors for ultraselective hydrogenations in the liquid phase†

Chun Wong Aaron Chan,a   Yaling Xie,a   Nick Cailuo,a   Kai Man Kerry Yu,a   James Cookson,b   Peter Bishopb  and  Shik Chi Tsang*a  

* Corresponding authors

a Wolfson Catalysis Centre, Department of Chemistry, University of Oxford, Oxford, UK
E-mail: edman.tsang@chem.ox.ac.uk

b Johnson Matthey Technology Centre, Blount's Court Road, Sonning Common, Reading, UK

Abstract

We report a novel preparation of a Pd nanocatalyst modified with subsurface C via blending a glucose precursor at the molecular level: the catalyst is demonstrated for the first time to be stereoselective in the hydrogenation of alkynes to cis-alkenes in the liquid phase.

Graphical abstract: New environmentally friendly catalysts containing Pd–interstitial carbon made from Pd–glucose precursors for ultraselective hydrogenations in the liquid phase

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Article information

DOI
https://doi.org/10.1039/C1CC12681D
Article type
Communication
Submitted
06 May 2011
Accepted
02 Jun 2011
First published
16 Jun 2011

Chem. Commun., 2011,47, 7971-7973

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New environmentally friendly catalysts containing Pd–interstitial carbon made from Pd–glucose precursors for ultraselective hydrogenations in the liquid phase

C. W. A. Chan, Y. Xie, N. Cailuo, K. M. K. Yu, J. Cookson, P. Bishop and S. C. Tsang, Chem. Commun., 2011, 47, 7971 DOI: 10.1039/C1CC12681D

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