Issue 38, 2011
From the journal:

Chemical Communications

Rhenium-catalyzed allylation of C–H bonds of benzoic and acrylic acids†

Yoichiro Kuninobu,*a   Kazuhiro Ohtaa  and  Kazuhiko Takai*a  

* Corresponding authors

a Division of Chemistry and Biochemistry, Graduate School of Natural Science and Technology, Okayama University, Tsushima, Kita-ku, Okayama 700-8530, Japan
E-mail: kuninobu@cc.okayama-u.ac.jp, ktakai@cc.okayama-u.ac.jp
Fax: +81-86-251-8094
Tel: +81-86-251-8095

Abstract

We have succeeded in the allylation of aromatic and olefinic C–H bonds of benzoic and acrylic acids using a rhenium catalyst, Re2(CO)10. In this reaction, isomerization of the introduced allyl group to the 1-propenyl group did not occur.

Graphical abstract: Rhenium-catalyzed allylation of C–H bonds of benzoic and acrylic acids

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Article information

DOI
https://doi.org/10.1039/C1CC12359A
Article type
Communication
Submitted
22 Apr 2011
Accepted
03 Aug 2011
First published
05 Sep 2011

Chem. Commun., 2011,47, 10791-10793

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Rhenium-catalyzed allylation of C–H bonds of benzoic and acrylic acids

Y. Kuninobu, K. Ohta and K. Takai, Chem. Commun., 2011, 47, 10791 DOI: 10.1039/C1CC12359A

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