Issue 24, 2011
From the journal:

Chemical Communications

Synthesis of a head-to-tail-type cyclodextrin-based insulated molecular wire†

Jun Terao,*a   Kazuhiro Ikai,b   Nobuaki Kambe,b   Shu Seki,*b   Akinori Saeki,b   Kento Ohkoshi,c   Tetsuaki Fujiharaa  and  Yasushi Tsujia  

* Corresponding authors

a Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, and PRESTO, Japan Science and Technology Agency (JST), Kyoto 615-8510, Japan
E-mail: terao@scl.kyoto-u.ac.jp
Fax: +81-75-383-2516
Tel: +81-75-383-2514

b Department of Applied Chemistry, Graduate School of Engineering, Osaka University, and PRESTO, Japan Science and Technology Agency (JST), Yamadaoka 2-1, Suita, Osaka 565-0871, Japan
E-mail: seki@chem.eng.osaka-u.ac.jp
Tel: +81-6-6879-4586

c Department of Polymer Chemistry, Tokyo Institute of Technology, Ookayama, Meguro-ku, Tokyo 152-8552, Japan

Abstract

We developed a new method for synthesizing an organic-soluble insulated molecular wire (IMW) using permethylated cyclodextrin (PMCD). The IMW obtained using this method is highly soluble in a variety of organic solvents and has a high covering ratio, regioregularity, rigidity, photoluminescence efficiency, and interchain hole mobility.

Graphical abstract: Synthesis of a head-to-tail-type cyclodextrin-based insulated molecular wire

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Article information

DOI
https://doi.org/10.1039/C1CC12231B
Article type
Communication
Submitted
18 Apr 2011
Accepted
09 May 2011
First published
23 May 2011

Chem. Commun., 2011,47, 6816-6818

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Synthesis of a head-to-tail-type cyclodextrin-based insulated molecular wire

J. Terao, K. Ikai, N. Kambe, S. Seki, A. Saeki, K. Ohkoshi, T. Fujihara and Y. Tsuji, Chem. Commun., 2011, 47, 6816 DOI: 10.1039/C1CC12231B

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