Issue 27, 2011
From the journal:

Chemical Communications

Binaphthyl platform as starting materials for the preparation of electron rich benzo[g,h,i]perylenes. Application to molecular architectures based on amino benzo[g,h,i]perylenes and carborane combinations†

Grégory Pieters,a   Anne Gaucher,*a   Damien Prim,a   Thierry Besson,b   José Giner Planas,*c   Francesc Teixidor,c   Clara Viñas,c   Mark E. Lightd  and  Michael B. Hursthoused  

* Corresponding authors

a Université de Versailles-Saint-Quentin-en-Yvelines, Institut Lavoisier de Versailles, UMR CNRS 8180, 45, Avenue des Etats-Unis, 78035 Versailles, France
E-mail: anne.gaucher@chimie.uvsq.fr, prim@chimie.uvsq.fr
Fax: +33 1 39254452
Tel: +33 1 39254454

b Université de Rouen-CNRS UMR 6014 & FR3038, IRCOF (Research Institute in Fine Organic Chemistry)rue Tesnière, 76130 Mont Saint Aignan, France

c Institut de Ciència de Materials de Barcelona (ICMAB-CSIC), Campus de la UAB, 08193 Bellaterra, Spain
E-mail: jginerplanas@icmab.es
Fax: +34 93 580 57 29
Tel: +34 93 580 18 53 (Ext. 361)

d School of Chemistry, University of Southampton, Highfield, Southampton, UK

Abstract

Valuable amino benzo[g,h,i]perylenes have been obtained through a one pot electrophilic aromatic substitution—Scholl reaction sequence. Novel molecular architectures combining 3D-o-carborane and planar amino benzo[g,h,i]perylene units are described. Photophysical properties of amino benzo[g,h,i]perylene and the carborane-appended derivatives are discussed.

Graphical abstract: Binaphthyl platform as starting materials for the preparation of electron rich benzo[g,h,i]perylenes. Application to molecular architectures based on amino benzo[g,h,i]perylenes and carborane combinations

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Article information

DOI
https://doi.org/10.1039/C1CC12099A
Article type
Communication
Submitted
12 Apr 2011
Accepted
17 May 2011
First published
07 Jun 2011

Chem. Commun., 2011,47, 7725-7727

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Binaphthyl platform as starting materials for the preparation of electron rich benzo[g,h,i]perylenes. Application to molecular architectures based on amino benzo[g,h,i]perylenes and carborane combinations

G. Pieters, A. Gaucher, D. Prim, T. Besson, J. Giner Planas, F. Teixidor, C. Viñas, M. E. Light and M. B. Hursthouse, Chem. Commun., 2011, 47, 7725 DOI: 10.1039/C1CC12099A

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