Issue 24, 2011
From the journal:

Chemical Communications

Addition of halide to π-bond directly from aqueous NaX solution: a general strategy for installation of two different functional groups†

Palash Pandit,a   Krishnanka S. Gayen,a   Saikat Khamarui,a   Nirbhik Chatterjeea  and  Dilip K. Maiti*a  

* Corresponding authors

a Department of Chemistry, University of Calcutta, University College of Science, 92, A. P. C. Road, Kolkata-700009, India
E-mail: maitidk@yahoo.com
Fax: +91-33-2351-9755
Tel: +91-33-2350-9937

Abstract

Activation of π-bond with organic Lewis acid and cationic surfactant mediated direct transfer of halides to alkyne and alkene are demonstrated to afford α,α-dihaloketones and other valuable synthons with outstanding selectivities.

Graphical abstract: Addition of halide to π-bond directly from aqueous NaX solution: a general strategy for installation of two different functional groups

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Article information

DOI
https://doi.org/10.1039/C1CC11685A
Article type
Communication
Submitted
24 Mar 2011
Accepted
04 May 2011
First published
20 May 2011

Chem. Commun., 2011,47, 6933-6935

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Addition of halide to π-bond directly from aqueous NaX solution: a general strategy for installation of two different functional groups

P. Pandit, K. S. Gayen, S. Khamarui, N. Chatterjee and D. K. Maiti, Chem. Commun., 2011, 47, 6933 DOI: 10.1039/C1CC11685A

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