Issue 24, 2011
From the journal:

Chemical Communications

Distinct magnetic dynamic behavior for two polymorphs of the same Dy(iii) complex†

Dong-Ping Li,‡a   Xiao-Peng Zhang,a   Tian-Wei Wang,a   Bin-Bin Ma,a   Cheng-Hui Li,*a   Yi-Zhi Lia  and  Xiao-Zeng You*a  

* Corresponding authors

a State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Nanjing University, Nanjing 210093, P. R. China
E-mail: chli@nju.edu.cn; youxz@nju.edu.cn
Fax: +86-25-83314502
Tel: +86-25-83592969

Abstract

Two polymorphs of the same Dy(III) complex show distinct slow magnetic relaxation behaviors due to the different local environments of Dy(III) in the crystal. This work represents the first example where the magnetic dynamic property of neutral rare earth complexes could be tuned by growing polymorphic crystals without changing the ligand.

Graphical abstract: Distinct magnetic dynamic behavior for two polymorphs of the same Dy(iii) complex

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Article information

DOI
https://doi.org/10.1039/C1CC11659B
Article type
Communication
Submitted
23 Mar 2011
Accepted
27 Apr 2011
First published
20 May 2011

Chem. Commun., 2011,47, 6867-6869

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Distinct magnetic dynamic behavior for two polymorphs of the same Dy(III) complex

D. Li, X. Zhang, T. Wang, B. Ma, C. Li, Y. Li and X. You, Chem. Commun., 2011, 47, 6867 DOI: 10.1039/C1CC11659B

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