Issue 34, 2011
From the journal:

Chemical Communications

Synthesis of 1,3,5-alternate azacalix[3]pyridine[3]pyrimidine and its complexation with fullerenesvia multiple π/π and CH/π interactions†

Li-Xia Wang,a   Liang Zhao,b   De-Xian Wanga  and  Mei-Xiang Wang*ab  

* Corresponding authors

a Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China

b The Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology (Ministry of Education), Department of Chemistry, Tsinghua University, Beijing 100084, China
E-mail: wangmx@mail.tsinghua.edu.cn
Fax: +8610-62796761

Abstract

Azacalix[3]pyridine[3]pyrimidine was synthesized efficiently by means of a [3+3] fragment coupling approach. Adopting a preorganized symmetric 1,3,5-alternate conformation, the macrocycle formed complexes with fullerenes through the multiple intramolecular π/π and CH/π interactions.

Graphical abstract: Synthesis of 1,3,5-alternate azacalix[3]pyridine[3]pyrimidine and its complexation with fullerenesvia multiple π/π and CH/π interactions

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Article information

DOI
https://doi.org/10.1039/C1CC11514F
Article type
Communication
Submitted
16 Mar 2011
Accepted
06 Jul 2011
First published
19 Jul 2011

Chem. Commun., 2011,47, 9690-9692

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Synthesis of 1,3,5-alternate azacalix[3]pyridine[3]pyrimidine and its complexation with fullerenesvia multiple π/π and CH/π interactions

L. Wang, L. Zhao, D. Wang and M. Wang, Chem. Commun., 2011, 47, 9690 DOI: 10.1039/C1CC11514F

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