Synthesis of the B-secolimonoid scaffold†
Abstract
The underlying stereochemically complex and densely functionalized scaffold of the B-secolimonoids was synthesized employing an Ireland–Claisen rearrangement as key transformation.
* Corresponding authors
a
Max-Planck-Institut für molekulare Physiologie, Chemische Biologie, Otto-Hahn-Str. 11, D-44227 Dortmund, Germany
E-mail:
herbert.waldmann@mpi-dortmund.mpg.de
Fax: +49 231 133 2499
b Technische Universität Dortmund, Fakultät Chemie, Chemische Biologie, Otto-Hahn-Str. 6, D-44227 Dortmund, Germany
c Universität Duisburg-Essen, Zentrum für medizinische Biotechnologie, Chemische Biologie, Universitätsstraße, D-45117 Essen, Germany
d Chemical Genomics Centre of the Max Planck Society, Otto-Hahn-Str. 15, D-44227 Dortmund, Germany
The underlying stereochemically complex and densely functionalized scaffold of the B-secolimonoids was synthesized employing an Ireland–Claisen rearrangement as key transformation.
H. Schuster, R. Martinez, H. Bruss, A. P. Antonchick, M. Kaiser, M. Schürmann and H. Waldmann, Chem. Commun., 2011, 47, 6545 DOI: 10.1039/C1CC11388G
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