Issue 16, 2011
From the journal:

Chemical Communications

A luminescent gold(i)–copper(i) cluster with unprecedented carbon-centered trigonal prismatic hexagold†

Jian-Hua Jia,a   Jing-Xia Liang,a   Zhen Lei,a   Ze-Xing Caoa  and  Quan-Ming Wang*a  

* Corresponding authors

a State Key Lab of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, Fujian 361005, P. R. China
E-mail: qmwang@xmu.edu.cn
Fax: +86 592-2183047
Tel: +86 592-2184185

Abstract

An unprecedented trigonal prismatic (μ6-C)Au6 structure has been found in a novel gold(I)–copper(I) cluster with a hypercoordinated carbon, [CAu6Cu2(dppy)6](BF4)4; the incorporation of copper ions enhances the rigidity and integrity of the cluster and turns on the bright red solution luminescence.

Graphical abstract: A luminescent gold(i)–copper(i) cluster with unprecedented carbon-centered trigonal prismatic hexagold

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Article information

DOI
https://doi.org/10.1039/C1CC10497G
Article type
Communication
Submitted
25 Jan 2011
Accepted
28 Feb 2011
First published
15 Mar 2011

Chem. Commun., 2011,47, 4739-4741

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A luminescent gold(I)–copper(I) cluster with unprecedented carbon-centered trigonal prismatic hexagold

J. Jia, J. Liang, Z. Lei, Z. Cao and Q. Wang, Chem. Commun., 2011, 47, 4739 DOI: 10.1039/C1CC10497G

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