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Issue 12, 2011
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Syntheses and structures of triazides of heavy group 15 elements

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Abstract

Synthesis of group 15-triazides E(N3)3 (E = Sb 1, Bi 2) and Py2–Bi(N3)33 (Py = pyridine). Single crystals of 1 were in situ grown by an IR-laser-assisted technique on the diffractometer. The structure of 3, which represents the first structurally characterized neutral Bi-triazide, is influenced by crystal packing effects according to DFT calculations.

Graphical abstract: Syntheses and structures of triazides of heavy group 15 elements

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Article information


Submitted
13 Jan 2011
Accepted
03 Feb 2011
First published
18 Feb 2011

Chem. Commun., 2011,47, 3401-3403
Article type
Communication

Syntheses and structures of triazides of heavy group 15 elements

S. Schulz, B. Lyhs, G. Jansen, D. Bläser and C. Wölper, Chem. Commun., 2011, 47, 3401
DOI: 10.1039/C1CC10237K

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