Issue 20, 2011
From the journal:

Chemical Communications

An eleven-vertex deltahedron with hexacapped trigonal bipyramidal geometry†

C. W. Liu,*a   Ping-Kuei Liao,a   Ching-Shiang Fang,a   Jean-Yves Saillard,*b   Samia Kahlalb  and  Ju-Chun Wangc  

* Corresponding authors

a Department of Chemistry, National Dong Hwa University, Hualien, Taiwan 97401, R.O.C
E-mail: chenwei@mail.ndhu.edu.tw
Fax: +866-3-863 3570
Tel: +886-3-863 3607

b UMR-CNRS, 6226 “Sciences Chimiques de Rennes”, Université de Rennes 1, 35042 Rennes Cedex, France
E-mail: jean-yves.saillard@univ-rennes1.fr

c Department of Chemistry, Soochow University, Taipei, Taiwan 111, ROC

Abstract

The first elemental cluster with hexacapped trigonal bipyramidal geometry is revealed in the luminescent undecanuclear silver complex which is stabilized by nine dithiocarbamate ligands and has an interstitial hydride. The hydride position within the Ag11 cage is confirmed by a DFT investigation.

Graphical abstract: An eleven-vertex deltahedron with hexacapped trigonal bipyramidal geometry

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C1CC10168D
Article type
Communication
Submitted
10 Jan 2011
Accepted
25 Mar 2011
First published
12 Apr 2011

Chem. Commun., 2011,47, 5831-5833

Permissions

Request permissions

An eleven-vertex deltahedron with hexacapped trigonal bipyramidal geometry

C. W. Liu, P. Liao, C. Fang, J. Saillard, S. Kahlal and J. Wang, Chem. Commun., 2011, 47, 5831 DOI: 10.1039/C1CC10168D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements