Issue 14, 2011
From the journal:

Chemical Communications

First proton triggered C–ON bond homolysis in alkoxyamines†

Paul Brémonda  and  Sylvain R. A. Marque*a  

* Corresponding authors

a Laboratoire Chimie Provence LCP-UMR6264, Université Aix-Marseille 1 – 3, case 521, Avenue Escadrille Normandie-Niemen, 13397 Marseille Cedex 20, France
E-mail: sylvain.marque@univ-provence.fr
Fax: +33 (0)4-91-28-87-58
Tel: +33 (0)4-91-28-80-46

Abstract

Rate constants kd of the C–ON bond homolysis in a new type of alkoxyamines (initiator/controller for Nitroxide Mediated Polymerization) carrying alkyl fragments capable of protonation were measured. A 20-fold increase was reported for the protonated alkoxyamine compared to the non-protonated homologue as predicted (Chem. Soc. Rev., 2011).

Graphical abstract: First proton triggered C–ON bond homolysis in alkoxyamines

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Article information

DOI
https://doi.org/10.1039/C0CC05637E
Article type
Communication
Submitted
17 Dec 2010
Accepted
09 Feb 2011
First published
28 Feb 2011

Chem. Commun., 2011,47, 4291-4293

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First proton triggered C–ON bond homolysis in alkoxyamines

P. Brémond and S. R. A. Marque, Chem. Commun., 2011, 47, 4291 DOI: 10.1039/C0CC05637E

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