Issue 16, 2011
From the journal:

Chemical Communications

Direct synthesis of ester-containing indium homoenolate and its application in palladium-catalyzed cross-coupling with aryl halide†

Zhi-Liang Shen,a   Kelvin Kau Kiat Goh,a   Colin Hong An Wong,a   Yong-Sheng Yang,a   Yin-Chang Lai,a   Hao-Lun Cheonga  and  Teck-Peng Loh*a  

* Corresponding authors

a Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore
E-mail: teckpeng@ntu.edu.sg
Fax: +65-67911961

Abstract

An efficient method for the synthesis of ester-containing indium homoenolatevia a direct insertion of indium into β-halo ester in the presence of CuI/LiCl was described. The synthetic utility of the indium homoenolate was demonstrated by palladium-catalyzed cross-coupling with aryl halides in DMA with wide functional group compatibility.

Graphical abstract: Direct synthesis of ester-containing indium homoenolate and its application in palladium-catalyzed cross-coupling with aryl halide

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Article information

DOI
https://doi.org/10.1039/C0CC05597B
Article type
Communication
Submitted
15 Dec 2010
Accepted
22 Feb 2011
First published
17 Mar 2011

Chem. Commun., 2011,47, 4778-4780

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Direct synthesis of ester-containing indium homoenolate and its application in palladium-catalyzed cross-coupling with aryl halide

Z. Shen, K. K. K. Goh, C. H. A. Wong, Y. Yang, Y. Lai, H. Cheong and T. Loh, Chem. Commun., 2011, 47, 4778 DOI: 10.1039/C0CC05597B

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