Issue 12, 2011
From the journal:

Chemical Communications

Clarification of a misconception in the BINOL-based fluorescent sensors: synthesis and study of major-groove BINOL-amino alcohols†

Hai-Lin Liu,a   Qiao-Ling Zhao,b   Xue-Long Hou*a  and  Lin Pu*c  

* Corresponding authors

a State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Ling Ling Rd, Shanghai 200032, China
E-mail: xlhou@mail.sioc.ac.c

b Division of Material Characterization, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Ling Ling Rd, Shanghai 200032, China

c Department of Chemistry, University of Virginia, Charlottesville, Virginia 22904, USA
E-mail: lp6n@virginia.edu

Abstract

The major-groove BINOL-amino alcohol (S)-6 shows greatly enhanced fluorescence over the minor-groove one (S)-3. The study of a series of the major-groove BINOL-amino alcohol compounds demonstrates that the commonly accepted acid inhibition of the PET fluorescence quenching of aryl-amine compounds is not involved in the BINOL-amine sensors.

Graphical abstract: Clarification of a misconception in the BINOL-based fluorescent sensors: synthesis and study of major-groove BINOL-amino alcohols

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Article information

DOI
https://doi.org/10.1039/C0CC05514J
Article type
Communication
Submitted
11 Dec 2010
Accepted
27 Jan 2011
First published
15 Feb 2011

Chem. Commun., 2011,47, 3646-3648

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Clarification of a misconception in the BINOL-based fluorescent sensors: synthesis and study of major-groove BINOL-amino alcohols

H. Liu, Q. Zhao, X. Hou and L. Pu, Chem. Commun., 2011, 47, 3646 DOI: 10.1039/C0CC05514J

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