Issue 11, 2011

A synthetic approach to a fullerene-rich dendron and its linear polymerviaring-opening metathesis polymerization

Abstract

Through the esterification of an acyl chloride functionalized fullerene precursor with dendritic alcohol, a fullerene-rich dendron containing a norbornene unit at the focal point is prepared for ring-opening metathesis polymerization to obtain its linear polymer with a unimodal and narrow molar mass distribution (PDI = 1.08) by a progressive addition of catalysts.

Graphical abstract: A synthetic approach to a fullerene-rich dendron and its linear polymerviaring-opening metathesis polymerization

Supplementary files

Article information

Article type
Communication
Submitted
09 Dec 2010
Accepted
21 Jan 2011
First published
10 Feb 2011

Chem. Commun., 2011,47, 3078-3080

A synthetic approach to a fullerene-rich dendron and its linear polymerviaring-opening metathesis polymerization

J. Kim, M. H. Yun, J. Lee, J. Y. Kim, F. Wudl and C. Yang, Chem. Commun., 2011, 47, 3078 DOI: 10.1039/C0CC05470D

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