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Issue 12, 2011
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SN2′ addition/1,2-elimination of dimethylsulfonium methylide with epoxy vinyl sulfones: synthesis of exocyclic cross-conjugated dienyl sulfones

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Abstract

Dimethylsulfonium methylide undergoes SN2′ addition/1,2-elimination with epoxy vinyl sulfones to generate enantiopure six and seven membered cross-conjugated hydroxy vinyl sulfones. Moderate to excellent yields were obtained for both six and seven membered substrates.

Graphical abstract: SN2′ addition/1,2-elimination of dimethylsulfonium methylide with epoxy vinyl sulfones: synthesis of exocyclic cross-conjugated dienyl sulfones

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Publication details

The article was received on 06 Dec 2010, accepted on 17 Jan 2011 and first published on 09 Feb 2011


Article type: Communication
DOI: 10.1039/C0CC05405D
Chem. Commun., 2011,47, 3472-3474

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    SN2′ addition/1,2-elimination of dimethylsulfonium methylide with epoxy vinyl sulfones: synthesis of exocyclic cross-conjugated dienyl sulfones

    V. Sikervar and P. L. Fuchs, Chem. Commun., 2011, 47, 3472
    DOI: 10.1039/C0CC05405D

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