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Issue 11, 2011
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A non-iterative, flexible, and highly stereoselective synthesis of polydeoxypropionates—synthesis of (+)-vittatalactone

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Abstract

A short sequence comprising an oxy-Cope rearrangement, iridium-catalyzed hydrogenation, and enolate methylation provides trideoxypropionates with excellent diastereocontrol. A straightforward synthesis of the cucumber beetle pheromone (+)-vittatalactone illustrates this new strategy.

Graphical abstract: A non-iterative, flexible, and highly stereoselective synthesis of polydeoxypropionates—synthesis of (+)-vittatalactone

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Publication details

The article was received on 26 Nov 2010, accepted on 11 Jan 2011 and first published on 28 Jan 2011


Article type: Communication
DOI: 10.1039/C0CC05215A
Chem. Commun., 2011,47, 3248-3250

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    A non-iterative, flexible, and highly stereoselective synthesis of polydeoxypropionates—synthesis of (+)-vittatalactone

    C. F. Weise, M. Pischl, A. Pfaltz and C. Schneider, Chem. Commun., 2011, 47, 3248
    DOI: 10.1039/C0CC05215A

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