Experimental charge density distribution of non-coordinating sp3 carbanions in [Mg{(pz*)3C}2]

Daniel Kratzert; Dirk Leusser; Daniel Stern; Jens Meyer; Frank Breher; Dietmar Stalke

doi:10.1039/C0CC04688D

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Experimental charge density distribution of non-coordinating sp³ carbanions in [Mg{(pz*)₃C}₂]†

Daniel Kratzert,^a Dirk Leusser,^a Daniel Stern,^a Jens Meyer,^b Frank Breher^b and Dietmar Stalke*^a

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* Corresponding authors

^a Institut für Anorganische Chemie der Universität Göttingen, Tammannstraße 4, 37077 Göttingen, Germany
E-mail: dstalke@chemie.uni-goettingen.de
Fax: +49 551-39-3459

^b Institut für Anorganische Chemie des Karlsruher Institut für Technologie (KIT), Engesserstraße 15, 76131 Karlsruhe, Germany

Abstract

In this communication we present the experimental charge density distribution in [Mg{(pz*)₃C}₂] (1), (pz* = 3,5-dimethylpyrazolyl), containing two non-coordinating sp³ carbanionic lone-pairs.

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Article information

DOI: https://doi.org/10.1039/C0CC04688D
Article type: Communication
Submitted: 29 Oct 2010
Accepted: 24 Dec 2010
First published: 24 Jan 2011

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Chem. Commun., 2011,47, 2931-2933

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Experimental charge density distribution of non-coordinating sp³ carbanions in [Mg{(pz*)₃C}₂]

D. Kratzert, D. Leusser, D. Stern, J. Meyer, F. Breher and D. Stalke, Chem. Commun., 2011, 47, 2931 DOI: 10.1039/C0CC04688D

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