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Issue 10, 2011
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Direct covalent post-synthetic chemical modification of Cr-MIL-101 using nitrating acid

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Abstract

For the first time, functionality has been covalently introduced into the Cr-MIL-101 network by post-synthetic modification of the terephthalate linker molecule through nitration. The nitro group was reduced and the amino group was reacted with ethyl isocyanate to yield the corresponding urea derivative.

Graphical abstract: Direct covalent post-synthetic chemical modification of Cr-MIL-101 using nitrating acid

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Supplementary files

Article information


Submitted
20 Oct 2010
Accepted
07 Jan 2011
First published
21 Jan 2011

Chem. Commun., 2011,47, 2838-2840
Article type
Communication

Direct covalent post-synthetic chemical modification of Cr-MIL-101 using nitrating acid

S. Bernt, V. Guillerm, C. Serre and N. Stock, Chem. Commun., 2011, 47, 2838
DOI: 10.1039/C0CC04526H

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