Issue 6, 2011
From the journal:

Chemical Communications

Confinement of halide ions within homologous inverse coordination hosts; modification of halide-ion selectivity†

Felipe García,a   Robert J. Less,a   Mary McPartlin,a   Annette Michalski,a   Robert E. Mulvey,b   Vesal Naseri,a   Matthew L. Stead,a   Ana Morán de Vegaa  and  Dominic S. Wright*a  

* Corresponding authors

a Chemistry Department, Cambridge University, Lensfield Road, Cambridge CB2 1EW, UK
E-mail: dsw1000@cam.ac.uk

b WestCHEM, Department of Pure and Applied Chemistry, University of Strathclyde, Glasgow G1 1XL, Scotland, UK

Abstract

The structures of a series of spherical host–guest complexes [{MeE(PPh)3Li4·3thf}4(μ4-X)]− (E = Al, [1X]−; E = Ga, [2X]−; E = In, [3X]−) reveal that changing the halide ions (X = Cl, Br, or I) within their central tetrahedral Li4 sites has negligible effect on the structural parameters.

Graphical abstract: Confinement of halide ions within homologous inverse coordination hosts; modification of halide-ion selectivity

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Article information

DOI
https://doi.org/10.1039/C0CC04483K
Article type
Communication
Submitted
18 Oct 2010
Accepted
23 Nov 2010
First published
06 Dec 2010

Chem. Commun., 2011,47, 1821-1823

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Confinement of halide ions within homologous inverse coordination hosts; modification of halide-ion selectivity

F. García, R. J. Less, M. McPartlin, A. Michalski, R. E. Mulvey, V. Naseri, M. L. Stead, A. Morán de Vega and D. S. Wright, Chem. Commun., 2011, 47, 1821 DOI: 10.1039/C0CC04483K

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