Issue 7, 2011
From the journal:

Chemical Communications

Temperature-dependent crystal structure of the isopropanol clathrate of Dianin's compound†

Jackson J. Lee,a   Rebecca O. Fuller,a   Alexandre N. Sobolev,a   Henrik F. Clausen,b   Jacob Overgaard,b   George A. Koutsantonis,a   Bo B. Iversenb  and  Mark A. Spackman*a  

* Corresponding authors

a Chemistry—M313, School of Biomedical, Biomolecular & Chemical Sciences, University of Western Australia, Crawley, WA, Australia
E-mail: mark.spackman@uwa.edu.au
Fax: +61 8 6488 1005

b Center for Materials Crystallography, Department of Chemistry and iNANO, Aarhus University, Århus C, Denmark
E-mail: bo@chem.ac.dk
Fax: +45 8619 6199

Abstract

The title compound undergoes two order–disorder transitions between 15 and 299 K, dictated by ordering of the guest molecules in the host cages, and resulting in three related crystal structures. We anticipate behaviour of this kind to be widespread, and speculate that the concept of “the crystal structure” for individual Dianin's clathrates may be elusive.

Graphical abstract: Temperature-dependent crystal structure of the isopropanol clathrate of Dianin's compound

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Article information

DOI
https://doi.org/10.1039/C0CC04418K
Article type
Communication
Submitted
15 Oct 2010
Accepted
10 Dec 2010
First published
06 Jan 2011

Chem. Commun., 2011,47, 2029-2031

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Temperature-dependent crystal structure of the isopropanol clathrate of Dianin's compound

J. J. Lee, R. O. Fuller, A. N. Sobolev, H. F. Clausen, J. Overgaard, G. A. Koutsantonis, B. B. Iversen and M. A. Spackman, Chem. Commun., 2011, 47, 2029 DOI: 10.1039/C0CC04418K

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